Pamukkale Univ Muh Bilim Derg. 2017; 23(7): 899-907 | DOI: 10.5505/pajes.2016.76735

Salisilik asit türevleri ile 2-aminobenzotiyazol türevlerinin karýþýk ligandlý Cu(II) komplekslerinin sentezi ve karakterizasyonu

Halil Ýlkimen, Cengiz Yenikaya
Dumlupýnar Üniversitesi, Fen-Edebiyat Fakültesi Kimya Bölümü, 43100, Kütahya, TÜRKÝYE

Bu çalýþmada, salisilik asit türevleri [salisilik asit (H2sal) veya asetilsalisilik asit (Hasal)] ile 2-aminobenzotiyazol türevlerinin [2-aminobenzotiyazol (abt) veya 2-amino-6-klorobenzotiyazol (Clabt) veya 2-amino-6-metilbenzotiyazol (Meabt)] karýþýk ligandlý Cu(II) geçiþ metal kompleksleri sentezlenmiþtir. Amorf halde elde edilen geçiþ metal komplekslerinin yapýlarý elementel analiz, ICP-OES, FT-IR, UV-Vis, termal analiz, manyetik duyarlýlýk ve molar iletkenlik sonuçlarý dikkate alýnarak önerilmiþtir.

Anahtar Kelimeler: Salisilik asit türevleri, 2-aminobenzotiyazol türevleri, Metal kompleksleri

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Synthesis and characterization of mixed ligand Cu(II) complexes of salicylic acid derivatives with 2-aminobenzotiyazol derivatives

Halil Ýlkimen, Cengiz Yenikaya
Department of Chemistry, Faculty of Arts and Science, Dumlupýnar University, 43100 Kütahya, Turkey

In this study, mixed ligand transition metal complexes of Cu(II) have been prepared between salicylic acid derivatives [salicylic acid (H2sal) or acetylsalicylic acid (Hasal)] and 2-aminobenzothiazole derivatives [2-aminobenzothiazole (abt) or 2-amino-6-chlorobenzothiazole (Clabt) or 2-amino-6-methylbenzothiazole (Meabt)]. The structures of amorphous metal complexes have been proposed by evaluating the data obtained from elemental analysis, ICP-OES, FT-IR, UV-Vis, thermal analysis, magnetic susceptibility and molar conductivity studies.

Keywords: Salicylic acid derivatives, 2-aminobenzothiazole derivatives, Metal complexes

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